Switchable catalysis with a light-responsive cavitand

Orion B. Berryman; Aaron C. Sather; Agustí Lledó; Julius Rebek

doi:10.1002/anie.201105374

Switchable catalysis with a light-responsive cavitand

Orion B. Berryman
, Aaron C. Sather
, Agustí Lledó
, Julius Rebek

Scripps Research Institute
Institute for Research in Biomedicine

Producción científica: Contribución a una revista › Artículo científico › revisión exhaustiva

104 Citas (Scopus)

Resumen

Catalytic guest stars: A cavitand with an azobenzene wall adopts an introverted shape when irradiated with UV light. This conformation has been characterized in solution and the solid state and is used to control guest binding. By incorporating an organocatalyst guest, the rate of the Knoevenagel condensation is controlled with light.

Idioma original	Inglés
Páginas (desde-hasta)	9400-9403
Número de páginas	4
Publicación	Angewandte Chemie International Edition
Volumen	50
N.º	40
DOI	https://doi.org/10.1002/anie.201105374
Estado	Publicada - 26 sept 2011
Publicado de forma externa	Sí

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title = "Switchable catalysis with a light-responsive cavitand",

abstract = "Catalytic guest stars: A cavitand with an azobenzene wall adopts an introverted shape when irradiated with UV light. This conformation has been characterized in solution and the solid state and is used to control guest binding. By incorporating an organocatalyst guest, the rate of the Knoevenagel condensation is controlled with light.",

keywords = "Knoevenagel condensation, cavitands, host-guest systems, photo-switches, supramolecular catalysis",

author = "Berryman, \{Orion B.\} and Sather, \{Aaron C.\} and Agust{\'i} Lled{\'o} and Julius Rebek",

year = "2011",

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language = "English",

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AU - Berryman, Orion B.

AU - Sather, Aaron C.

AU - Lledó, Agustí

AU - Rebek, Julius

PY - 2011/9/26

Y1 - 2011/9/26

N2 - Catalytic guest stars: A cavitand with an azobenzene wall adopts an introverted shape when irradiated with UV light. This conformation has been characterized in solution and the solid state and is used to control guest binding. By incorporating an organocatalyst guest, the rate of the Knoevenagel condensation is controlled with light.

AB - Catalytic guest stars: A cavitand with an azobenzene wall adopts an introverted shape when irradiated with UV light. This conformation has been characterized in solution and the solid state and is used to control guest binding. By incorporating an organocatalyst guest, the rate of the Knoevenagel condensation is controlled with light.

KW - Knoevenagel condensation

KW - cavitands

KW - host-guest systems

KW - photo-switches

KW - supramolecular catalysis

UR - https://www.scopus.com/pages/publications/80053160629

U2 - 10.1002/anie.201105374

DO - 10.1002/anie.201105374

M3 - Scientific article

C2 - 21905192

AN - SCOPUS:80053160629

SN - 1433-7851

VL - 50

SP - 9400

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JO - Angewandte Chemie International Edition

JF - Angewandte Chemie International Edition

IS - 40

ER -

Switchable catalysis with a light-responsive cavitand

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