Dendritic phosphoramidite ligands for Rh-catalyzed [2+2+2] cycloaddition reactions: Unprecedented enhancement of enantiodiscrimination

Lídia Garcia; Anna Roglans; Régis Laurent; Jean Pierre Majoral; Anna Pla-Quintana; Anne Marie Caminade

doi:10.1039/c2cc32992a

Dendritic phosphoramidite ligands for Rh-catalyzed [2+2+2] cycloaddition reactions: Unprecedented enhancement of enantiodiscrimination

Lídia Garcia
, Anna Roglans
, Régis Laurent
, Jean Pierre Majoral
, Anna Pla-Quintana
, Anne Marie Caminade

University of Girona
CNRS

Producción científica: Contribución a una revista › Artículo científico › revisión exhaustiva

51 Citas (Scopus)

Resumen

Phosphorus dendrimers containing terminal phosphoramidite ligands have been found to be highly effective and recoverable catalysts for the rhodium(I) catalyzed [2+2+2] cycloaddition reactions. A strong positive dendritic effect is observed both in the activity and enantiodiscrimination leading to axially chiral biaryl compounds. 2012

Idioma original	Inglés
Páginas (desde-hasta)	9248-9250
Número de páginas	3
Publicación	Chemical Communications
Volumen	48
N.º	74
DOI	https://doi.org/10.1039/c2cc32992a
Estado	Publicada - 20 ago 2012

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10.1039/c2cc32992a

https://hdl.handle.net/10256/11345

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abstract = "Phosphorus dendrimers containing terminal phosphoramidite ligands have been found to be highly effective and recoverable catalysts for the rhodium(I) catalyzed [2+2+2] cycloaddition reactions. A strong positive dendritic effect is observed both in the activity and enantiodiscrimination leading to axially chiral biaryl compounds. 2012",

author = "L{\'i}dia Garcia and Anna Roglans and R{\'e}gis Laurent and Majoral, \{Jean Pierre\} and Anna Pla-Quintana and Caminade, \{Anne Marie\}",

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T1 - Dendritic phosphoramidite ligands for Rh-catalyzed [2+2+2] cycloaddition reactions

T2 - Unprecedented enhancement of enantiodiscrimination

AU - Garcia, Lídia

AU - Roglans, Anna

AU - Laurent, Régis

AU - Majoral, Jean Pierre

AU - Pla-Quintana, Anna

AU - Caminade, Anne Marie

PY - 2012/8/20

Y1 - 2012/8/20

N2 - Phosphorus dendrimers containing terminal phosphoramidite ligands have been found to be highly effective and recoverable catalysts for the rhodium(I) catalyzed [2+2+2] cycloaddition reactions. A strong positive dendritic effect is observed both in the activity and enantiodiscrimination leading to axially chiral biaryl compounds. 2012

AB - Phosphorus dendrimers containing terminal phosphoramidite ligands have been found to be highly effective and recoverable catalysts for the rhodium(I) catalyzed [2+2+2] cycloaddition reactions. A strong positive dendritic effect is observed both in the activity and enantiodiscrimination leading to axially chiral biaryl compounds. 2012

UR - https://www.scopus.com/pages/publications/84865255046

U2 - 10.1039/c2cc32992a

DO - 10.1039/c2cc32992a

M3 - Scientific article

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SP - 9248

EP - 9250

JO - Chemical Communications

JF - Chemical Communications

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ER -

Dendritic phosphoramidite ligands for Rh-catalyzed [2+2+2] cycloaddition reactions: Unprecedented enhancement of enantiodiscrimination

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