Reaction of Diphenyl Phosphorochloridate with Amide Enolates: A new and convenient synthesis of 2‐monosubstituted 3‐(n‐methyl‐n ‐phenylamino)‐2H‐azirines

José M. Villalgordo; Heinz Heimgartner

doi:10.1002/hlca.19920750612

Reaction of Diphenyl Phosphorochloridate with Amide Enolates: A new and convenient synthesis of 2‐monosubstituted 3‐(n‐methyl‐n ‐phenylamino)‐2H‐azirines

José M. Villalgordo
, Heinz Heimgartner

University of Zurich

Research output: Contribution to journal › Scientific article › peer-review

25 Citations (Scopus)

Abstract

Reaction of diphenyl phosphorochloridate with amide enolates and subsequent treatment with NaN₃ leads to 2‐monosubstituted 3‐amino‐2H ‐azirines 5 in moderate yields. The reactivity of these azirines is briefly explored.

Original language	English
Pages (from-to)	1866-1871
Number of pages	6
Journal	Helvetica Chimica Acta
Volume	75
Issue number	6
DOIs	https://doi.org/10.1002/hlca.19920750612
Publication status	Published - 2 Oct 1992
Externally published	Yes

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title = "Reaction of Diphenyl Phosphorochloridate with Amide Enolates: A new and convenient synthesis of 2‐monosubstituted 3‐(n‐methyl‐n ‐phenylamino)‐2H‐azirines",

abstract = "Reaction of diphenyl phosphorochloridate with amide enolates and subsequent treatment with NaN3 leads to 2‐monosubstituted 3‐amino‐2H ‐azirines 5 in moderate yields. The reactivity of these azirines is briefly explored.",

author = "Villalgordo, \{Jos{\'e} M.\} and Heinz Heimgartner",

year = "1992",

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T1 - Reaction of Diphenyl Phosphorochloridate with Amide Enolates

T2 - A new and convenient synthesis of 2‐monosubstituted 3‐(n‐methyl‐n ‐phenylamino)‐2H‐azirines

AU - Villalgordo, José M.

AU - Heimgartner, Heinz

PY - 1992/10/2

Y1 - 1992/10/2

N2 - Reaction of diphenyl phosphorochloridate with amide enolates and subsequent treatment with NaN3 leads to 2‐monosubstituted 3‐amino‐2H ‐azirines 5 in moderate yields. The reactivity of these azirines is briefly explored.

AB - Reaction of diphenyl phosphorochloridate with amide enolates and subsequent treatment with NaN3 leads to 2‐monosubstituted 3‐amino‐2H ‐azirines 5 in moderate yields. The reactivity of these azirines is briefly explored.

UR - https://www.scopus.com/pages/publications/0001122614

U2 - 10.1002/hlca.19920750612

DO - 10.1002/hlca.19920750612

M3 - Scientific article

AN - SCOPUS:0001122614

SN - 0018-019X

VL - 75

SP - 1866

EP - 1871

JO - Helvetica Chimica Acta

JF - Helvetica Chimica Acta

IS - 6

ER -

Reaction of Diphenyl Phosphorochloridate with Amide Enolates: A new and convenient synthesis of 2‐monosubstituted 3‐(n‐methyl‐n ‐phenylamino)‐2H‐azirines

Abstract

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