On the nature of the transition metal-main group metal bond: Synthesis and theoretical calculations on iridium gallyl complexes

Clara J. Durango-García; J. Oscar C. Jiménez-Halla; Marcela López-Cardoso; Virginia Montiel-Palma; Miguel A. Muñoz-Hernández; Gabriel Merino

doi:10.1039/c0dt01071e

On the nature of the transition metal-main group metal bond: Synthesis and theoretical calculations on iridium gallyl complexes

Clara J. Durango-García
, J. Oscar C. Jiménez-Halla
, Marcela López-Cardoso
, Virginia Montiel-Palma
, Miguel A. Muñoz-Hernández
, Gabriel Merino

Universidad Autonoma del Estado de Morelos
Universidad de Guanajuato

Research output: Contribution to journal › Scientific article › peer-review

26 Citations (Scopus)

Abstract

The iridum-gallyl complex MeIr(PCy₃)₂(GaMe ₂)(ClGaMe₃) exhibits a short Ir-Ga bond length of 2.381(1)-2.389(2) Å. Theoretical calculations (ZORA BP86/TZ2P) support the presence of a Ir-Ga single bond but highlight a π orbital contribution.

Original language	English
Pages (from-to)	10588-10589
Number of pages	2
Journal	Dalton Transactions
Volume	39
Issue number	44
DOIs	https://doi.org/10.1039/c0dt01071e
Publication status	Published - 28 Nov 2010
Externally published	Yes

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10.1039/c0dt01071e

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title = "On the nature of the transition metal-main group metal bond: Synthesis and theoretical calculations on iridium gallyl complexes",

abstract = "The iridum-gallyl complex MeIr(PCy3)2(GaMe 2)(ClGaMe3) exhibits a short Ir-Ga bond length of 2.381(1)-2.389(2) {\AA}. Theoretical calculations (ZORA BP86/TZ2P) support the presence of a Ir-Ga single bond but highlight a π orbital contribution.",

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T2 - Synthesis and theoretical calculations on iridium gallyl complexes

AU - Durango-García, Clara J.

AU - Jiménez-Halla, J. Oscar C.

AU - López-Cardoso, Marcela

AU - Montiel-Palma, Virginia

AU - Muñoz-Hernández, Miguel A.

AU - Merino, Gabriel

PY - 2010/11/28

Y1 - 2010/11/28

N2 - The iridum-gallyl complex MeIr(PCy3)2(GaMe 2)(ClGaMe3) exhibits a short Ir-Ga bond length of 2.381(1)-2.389(2) Å. Theoretical calculations (ZORA BP86/TZ2P) support the presence of a Ir-Ga single bond but highlight a π orbital contribution.

AB - The iridum-gallyl complex MeIr(PCy3)2(GaMe 2)(ClGaMe3) exhibits a short Ir-Ga bond length of 2.381(1)-2.389(2) Å. Theoretical calculations (ZORA BP86/TZ2P) support the presence of a Ir-Ga single bond but highlight a π orbital contribution.

UR - https://www.scopus.com/pages/publications/78049361348

U2 - 10.1039/c0dt01071e

DO - 10.1039/c0dt01071e

M3 - Scientific article

AN - SCOPUS:78049361348

SN - 1477-9226

VL - 39

SP - 10588

EP - 10589

JO - Dalton Transactions

JF - Dalton Transactions

IS - 44

ER -

On the nature of the transition metal-main group metal bond: Synthesis and theoretical calculations on iridium gallyl complexes

Abstract

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