Intermolecular hydrogen bonding in calix[5]arene derived cavitands regulates the molecular recognition of fullerenes

Rubén Álvarez-Yebra; Alba Sors-Vendrell; Agustí Lledó

doi:10.1039/d3cc03780k

Intermolecular hydrogen bonding in calix[5]arene derived cavitands regulates the molecular recognition of fullerenes

Rubén Álvarez-Yebra
, Alba Sors-Vendrell
, Agustí Lledó

University of Girona

Research output: Contribution to journal › Scientific article › peer-review

8 Citations (Scopus)

Abstract

We present a readily available calix[5]arene derived cavitand receptor that is stabilized in the closed cone conformer through intermolecular hydrogen bonding with methanol molecules. The receptor features a highly spherical aromatic surface that binds C₆₀ and C₇₀ fullerenes effectively, and the binding event can be regulated allosterically by the addition of methanol.

Original language	English
Pages (from-to)	11556-11559
Number of pages	4
Journal	Chemical Communications
Volume	59
Issue number	77
DOIs	https://doi.org/10.1039/d3cc03780k
Publication status	Published - 1 Sept 2023

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title = "Intermolecular hydrogen bonding in calix[5]arene derived cavitands regulates the molecular recognition of fullerenes",

abstract = "We present a readily available calix[5]arene derived cavitand receptor that is stabilized in the closed cone conformer through intermolecular hydrogen bonding with methanol molecules. The receptor features a highly spherical aromatic surface that binds C60 and C70 fullerenes effectively, and the binding event can be regulated allosterically by the addition of methanol.",

author = "Rub{\'e}n {\'A}lvarez-Yebra and Alba Sors-Vendrell and Agust{\'i} Lled{\'o}",

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T1 - Intermolecular hydrogen bonding in calix[5]arene derived cavitands regulates the molecular recognition of fullerenes

AU - Álvarez-Yebra, Rubén

AU - Sors-Vendrell, Alba

AU - Lledó, Agustí

PY - 2023/9/1

Y1 - 2023/9/1

N2 - We present a readily available calix[5]arene derived cavitand receptor that is stabilized in the closed cone conformer through intermolecular hydrogen bonding with methanol molecules. The receptor features a highly spherical aromatic surface that binds C60 and C70 fullerenes effectively, and the binding event can be regulated allosterically by the addition of methanol.

AB - We present a readily available calix[5]arene derived cavitand receptor that is stabilized in the closed cone conformer through intermolecular hydrogen bonding with methanol molecules. The receptor features a highly spherical aromatic surface that binds C60 and C70 fullerenes effectively, and the binding event can be regulated allosterically by the addition of methanol.

UR - https://www.scopus.com/pages/publications/85171805367

U2 - 10.1039/d3cc03780k

DO - 10.1039/d3cc03780k

M3 - Scientific article

C2 - 37681250

AN - SCOPUS:85171805367

SN - 1359-7345

VL - 59

SP - 11556

EP - 11559

JO - Chemical Communications

JF - Chemical Communications

IS - 77

ER -

Intermolecular hydrogen bonding in calix[5]arene derived cavitands regulates the molecular recognition of fullerenes

Abstract

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