Fluorous aryl compounds by Matsuda-Heck reaction

Jordi Salabert; Rosa María Sebastián; Adelina Vallribera; Anna Roglans; Carmen Nájera

doi:10.1016/j.tet.2011.09.046

Fluorous aryl compounds by Matsuda-Heck reaction

Jordi Salabert
, Rosa María Sebastián
, Adelina Vallribera
, Anna Roglans
, Carmen Nájera

Department of Chemistry

Autonomous University of Barcelona
University of Alicante

Research output: Contribution to journal › Scientific article › peer-review

17 Citations (Scopus)

Abstract

Fluorous aryl compounds are obtained through the arylation of different electron-rich and electron-poor olefins with an arenediazonium salt bearing a fully fluorinated octyl-ponytail at the para position. The Matsuda-Heck reactions are catalyzed by Pd(OAc)₂ or 4-hydroxyacetophenone oxime-derived palladacycle as efficient sources of Pd nanoparticles, with loadings of 1 mol % Pd, at room temperature, in methanol and without the need to add external base.

Original language	English
Pages (from-to)	8659-8664
Number of pages	6
Journal	Tetrahedron
Volume	67
Issue number	45
DOIs	https://doi.org/10.1016/j.tet.2011.09.046
Publication status	Published - 11 Nov 2011

Keywords

Arenediazonium salt
Fluorous compounds
Matsuda-Heck
Nanoparticles
Palladacycle
Palladium

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10.1016/j.tet.2011.09.046

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title = "Fluorous aryl compounds by Matsuda-Heck reaction",

abstract = "Fluorous aryl compounds are obtained through the arylation of different electron-rich and electron-poor olefins with an arenediazonium salt bearing a fully fluorinated octyl-ponytail at the para position. The Matsuda-Heck reactions are catalyzed by Pd(OAc)2 or 4-hydroxyacetophenone oxime-derived palladacycle as efficient sources of Pd nanoparticles, with loadings of 1 mol \% Pd, at room temperature, in methanol and without the need to add external base.",

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author = "Jordi Salabert and Sebasti{\'a}n, \{Rosa Mar{\'i}a\} and Adelina Vallribera and Anna Roglans and Carmen N{\'a}jera",

year = "2011",

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T1 - Fluorous aryl compounds by Matsuda-Heck reaction

AU - Salabert, Jordi

AU - Sebastián, Rosa María

AU - Vallribera, Adelina

AU - Roglans, Anna

AU - Nájera, Carmen

PY - 2011/11/11

Y1 - 2011/11/11

N2 - Fluorous aryl compounds are obtained through the arylation of different electron-rich and electron-poor olefins with an arenediazonium salt bearing a fully fluorinated octyl-ponytail at the para position. The Matsuda-Heck reactions are catalyzed by Pd(OAc)2 or 4-hydroxyacetophenone oxime-derived palladacycle as efficient sources of Pd nanoparticles, with loadings of 1 mol % Pd, at room temperature, in methanol and without the need to add external base.

AB - Fluorous aryl compounds are obtained through the arylation of different electron-rich and electron-poor olefins with an arenediazonium salt bearing a fully fluorinated octyl-ponytail at the para position. The Matsuda-Heck reactions are catalyzed by Pd(OAc)2 or 4-hydroxyacetophenone oxime-derived palladacycle as efficient sources of Pd nanoparticles, with loadings of 1 mol % Pd, at room temperature, in methanol and without the need to add external base.

KW - Arenediazonium salt

KW - Fluorous compounds

KW - Matsuda-Heck

KW - Nanoparticles

KW - Palladacycle

KW - Palladium

UR - https://www.scopus.com/pages/publications/80053596822

U2 - 10.1016/j.tet.2011.09.046

DO - 10.1016/j.tet.2011.09.046

M3 - Scientific article

AN - SCOPUS:80053596822

SN - 0040-4020

VL - 67

SP - 8659

EP - 8664

JO - Tetrahedron

JF - Tetrahedron

IS - 45

ER -

Fluorous aryl compounds by Matsuda-Heck reaction

Abstract

Keywords

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