Dehydrogenative [2 + 2 + 2] Cycloaddition of Cyano-yne-allene Substrates: Convenient Access to 2,6-Naphthyridine Scaffolds

Ewelina Haraburda; Agustí Lledó; Anna Roglans; Anna Pla-Quintana

doi:10.1021/acs.orglett.5b01554

Dehydrogenative [2 + 2 + 2] Cycloaddition of Cyano-yne-allene Substrates: Convenient Access to 2,6-Naphthyridine Scaffolds

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Abstract

A rhodium-catalyzed [2 + 2 + 2] cycloaddition of cyano-yne-allene scaffolds followed by a dehydrogenative process enabling the direct synthesis of unsaturated pyridine-containing compounds that can be conveniently converted to 2,6-naphthyridine derivatives is reported.

Original language	English
Pages (from-to)	2882-2885
Number of pages	4
Journal	Organic Letters
Volume	17
Issue number	12
DOIs	https://doi.org/10.1021/acs.orglett.5b01554
Publication status	Published - 19 Jun 2015

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title = "Dehydrogenative [2 + 2 + 2] Cycloaddition of Cyano-yne-allene Substrates: Convenient Access to 2,6-Naphthyridine Scaffolds",

abstract = "A rhodium-catalyzed [2 + 2 + 2] cycloaddition of cyano-yne-allene scaffolds followed by a dehydrogenative process enabling the direct synthesis of unsaturated pyridine-containing compounds that can be conveniently converted to 2,6-naphthyridine derivatives is reported.",

author = "Ewelina Haraburda and Agust{\'i} Lled{\'o} and Anna Roglans and Anna Pla-Quintana",

note = "Publisher Copyright: {\textcopyright} 2015 American Chemical Society.",

year = "2015",

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doi = "10.1021/acs.orglett.5b01554",

language = "English",

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T1 - Dehydrogenative [2 + 2 + 2] Cycloaddition of Cyano-yne-allene Substrates

T2 - Convenient Access to 2,6-Naphthyridine Scaffolds

AU - Haraburda, Ewelina

AU - Lledó, Agustí

AU - Roglans, Anna

AU - Pla-Quintana, Anna

PY - 2015/6/19

Y1 - 2015/6/19

N2 - A rhodium-catalyzed [2 + 2 + 2] cycloaddition of cyano-yne-allene scaffolds followed by a dehydrogenative process enabling the direct synthesis of unsaturated pyridine-containing compounds that can be conveniently converted to 2,6-naphthyridine derivatives is reported.

AB - A rhodium-catalyzed [2 + 2 + 2] cycloaddition of cyano-yne-allene scaffolds followed by a dehydrogenative process enabling the direct synthesis of unsaturated pyridine-containing compounds that can be conveniently converted to 2,6-naphthyridine derivatives is reported.

UR - https://www.scopus.com/pages/publications/84934897504

U2 - 10.1021/acs.orglett.5b01554

DO - 10.1021/acs.orglett.5b01554

M3 - Scientific article

C2 - 26068506

AN - SCOPUS:84934897504

SN - 1523-7060

VL - 17

SP - 2882

EP - 2885

JO - Organic Letters

JF - Organic Letters

IS - 12

ER -

Dehydrogenative [2 + 2 + 2] Cycloaddition of Cyano-yne-allene Substrates: Convenient Access to 2,6-Naphthyridine Scaffolds

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