A simple catalytic system based on PdCl2(CH3CN) 2 in water for cross-coupling reactions using diazonium salts

Ouissam El Bakouri; Martí Fernández; Sandra Brun; Anna Pla-Quintana; Anna Roglans

doi:10.1016/j.tet.2013.09.010

A simple catalytic system based on PdCl₂(CH₃CN) ₂ in water for cross-coupling reactions using diazonium salts

Ouissam El Bakouri
, Martí Fernández
, Sandra Brun
, Anna Pla-Quintana
, Anna Roglans

Research output: Contribution to journal › Scientific article › peer-review

23 Citations (Scopus)

Abstract

Aryl-heteroaryl and heteroaryl-heteroaryl compounds are obtained through the Suzuki-Miyaura cross-coupling reactions between diazonium salts and potassium trifluoroborates using PdCl₂(CH₃CN)₂ as the catalyst in water and in the absence of any additive, ligand or base. In addition, the same mild catalytic system is effective for the Matsuda-Heck reaction between several monoolefins with aryldiazonium salts.

Original language	English
Pages (from-to)	9761-9765
Number of pages	5
Journal	Tetrahedron
Volume	69
Issue number	46
DOIs	https://doi.org/10.1016/j.tet.2013.09.010
Publication status	Published - 18 Nov 2013

Keywords

Aqueous medium
Cross-coupling reactions
Diazonium salts
Palladium

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10.1016/j.tet.2013.09.010

https://hdl.handle.net/10256/11338

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title = "A simple catalytic system based on PdCl2(CH3CN) 2 in water for cross-coupling reactions using diazonium salts",

abstract = "Aryl-heteroaryl and heteroaryl-heteroaryl compounds are obtained through the Suzuki-Miyaura cross-coupling reactions between diazonium salts and potassium trifluoroborates using PdCl2(CH3CN)2 as the catalyst in water and in the absence of any additive, ligand or base. In addition, the same mild catalytic system is effective for the Matsuda-Heck reaction between several monoolefins with aryldiazonium salts.",

keywords = "Aqueous medium, Cross-coupling reactions, Diazonium salts, Palladium",

author = "\{El Bakouri\}, Ouissam and Mart{\'i} Fern{\'a}ndez and Sandra Brun and Anna Pla-Quintana and Anna Roglans",

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doi = "10.1016/j.tet.2013.09.010",

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T1 - A simple catalytic system based on PdCl2(CH3CN) 2 in water for cross-coupling reactions using diazonium salts

AU - El Bakouri, Ouissam

AU - Fernández, Martí

AU - Brun, Sandra

AU - Pla-Quintana, Anna

AU - Roglans, Anna

PY - 2013/11/18

Y1 - 2013/11/18

N2 - Aryl-heteroaryl and heteroaryl-heteroaryl compounds are obtained through the Suzuki-Miyaura cross-coupling reactions between diazonium salts and potassium trifluoroborates using PdCl2(CH3CN)2 as the catalyst in water and in the absence of any additive, ligand or base. In addition, the same mild catalytic system is effective for the Matsuda-Heck reaction between several monoolefins with aryldiazonium salts.

AB - Aryl-heteroaryl and heteroaryl-heteroaryl compounds are obtained through the Suzuki-Miyaura cross-coupling reactions between diazonium salts and potassium trifluoroborates using PdCl2(CH3CN)2 as the catalyst in water and in the absence of any additive, ligand or base. In addition, the same mild catalytic system is effective for the Matsuda-Heck reaction between several monoolefins with aryldiazonium salts.

KW - Aqueous medium

KW - Cross-coupling reactions

KW - Diazonium salts

KW - Palladium

UR - https://www.scopus.com/pages/publications/84885179412

U2 - 10.1016/j.tet.2013.09.010

DO - 10.1016/j.tet.2013.09.010

M3 - Scientific article

AN - SCOPUS:84885179412

SN - 0040-4020

VL - 69

SP - 9761

EP - 9765

JO - Tetrahedron

JF - Tetrahedron

IS - 46

ER -

A simple catalytic system based on PdCl₂(CH₃CN) ₂ in water for cross-coupling reactions using diazonium salts

Abstract

Keywords

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