2D layered coordination polymer based on an unusual mixed valence Cu(III)/Cu(I) bis-1,2-diselenolene compound

Xavi Ribas; Daniel Maspoch; João Dias; Jorge Morgado; Manuel Almeida; Klaus Wurst; Gavin Vaughan; Jaume Veciana; Concepció Rovira

doi:10.1039/b415416a

2D layered coordination polymer based on an unusual mixed valence Cu(III)/Cu(I) bis-1,2-diselenolene compound

Xavi Ribas
, Daniel Maspoch
, João Dias
, Jorge Morgado
, Manuel Almeida
, Klaus Wurst
, Gavin Vaughan
, Jaume Veciana
, Concepció Rovira

CSIC - Institute of Materials Science of Barcelona
Instituto Tecnológico e Nuclear
University of Lisbon
University of Innsbruck
European Synchrotron Radiation Facility

Research output: Contribution to journal › Scientific article › peer-review

27 Citations (Scopus)

Abstract

The crystal structure of a new mixed-valence Cu(III)/Cu(I) compound containing the ligand pds^2- (pds, pyrazine-2,3-diselenolate) shows a unique packing pattern with 2D layers formed by the coordination of the Cu(I) countercations to both the pyrazine N and Se atoms of the [Cu ^III(pds)₂]^- complex, with a distorted square pyramidal environment for Cu(I) centres.

Original language	English
Pages (from-to)	589-592
Number of pages	4
Journal	CrystEngComm
Volume	6
DOIs	https://doi.org/10.1039/b415416a
Publication status	Published - 2 Nov 2004
Externally published	Yes

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10.1039/b415416a

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title = "2D layered coordination polymer based on an unusual mixed valence Cu(III)/Cu(I) bis-1,2-diselenolene compound",

abstract = "The crystal structure of a new mixed-valence Cu(III)/Cu(I) compound containing the ligand pds2- (pds, pyrazine-2,3-diselenolate) shows a unique packing pattern with 2D layers formed by the coordination of the Cu(I) countercations to both the pyrazine N and Se atoms of the [Cu III(pds)2]- complex, with a distorted square pyramidal environment for Cu(I) centres.",

author = "Xavi Ribas and Daniel Maspoch and Jo{\~a}o Dias and Jorge Morgado and Manuel Almeida and Klaus Wurst and Gavin Vaughan and Jaume Veciana and Concepci{\'o} Rovira",

year = "2004",

month = nov,

day = "2",

doi = "10.1039/b415416a",

language = "English",

volume = "6",

pages = "589--592",

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publisher = "Royal Society of Chemistry",

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T1 - 2D layered coordination polymer based on an unusual mixed valence Cu(III)/Cu(I) bis-1,2-diselenolene compound

AU - Ribas, Xavi

AU - Maspoch, Daniel

AU - Dias, João

AU - Morgado, Jorge

AU - Almeida, Manuel

AU - Wurst, Klaus

AU - Vaughan, Gavin

AU - Veciana, Jaume

AU - Rovira, Concepció

PY - 2004/11/2

Y1 - 2004/11/2

N2 - The crystal structure of a new mixed-valence Cu(III)/Cu(I) compound containing the ligand pds2- (pds, pyrazine-2,3-diselenolate) shows a unique packing pattern with 2D layers formed by the coordination of the Cu(I) countercations to both the pyrazine N and Se atoms of the [Cu III(pds)2]- complex, with a distorted square pyramidal environment for Cu(I) centres.

AB - The crystal structure of a new mixed-valence Cu(III)/Cu(I) compound containing the ligand pds2- (pds, pyrazine-2,3-diselenolate) shows a unique packing pattern with 2D layers formed by the coordination of the Cu(I) countercations to both the pyrazine N and Se atoms of the [Cu III(pds)2]- complex, with a distorted square pyramidal environment for Cu(I) centres.

UR - https://www.scopus.com/pages/publications/15944417546

U2 - 10.1039/b415416a

DO - 10.1039/b415416a

M3 - Scientific article

AN - SCOPUS:15944417546

SN - 1466-8033

VL - 6

SP - 589

EP - 592

JO - CrystEngComm

JF - CrystEngComm

ER -

2D layered coordination polymer based on an unusual mixed valence Cu(III)/Cu(I) bis-1,2-diselenolene compound

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