15-Membered triolefinic macrocycles, their coordination chemistry with transition metals, and the catalytic properties of their palladium metal complexes. A review

Marcial Moreno-Mañas; Roser Pleixats; Anna Roglans; Rosa M. Sebastián; Adelina Vallribera

15-Membered triolefinic macrocycles, their coordination chemistry with transition metals, and the catalytic properties of their palladium metal complexes. A review

Marcial Moreno-Mañas
, Roser Pleixats
, Anna Roglans
, Rosa M. Sebastián
, Adelina Vallribera

Department of Chemistry

Autonomous University of Barcelona

Research output: Contribution to journal › Review article › peer-review

34 Citations (Scopus)

Abstract

(E,E,E)-1,6,11-Tris(arenesulfonyl)-1,6,11-triazacyclopentadeca-3,8, 11-trienes, 1, are prepared from arenesulfonamides and trans-1,4-dibromo-2-butene. Macrocycles 1 coordinate palladium(0), platinum(0), and silver(I), and the palladium complexes are useful and reutilizable catalysts or precatalysts in Suzuki cross-couplings, butadiene telomerizations, hydroarylation of alkynes, and in the Heck reaction. Structurally related macrocycles are also available by similar synthetic procedures.

Original language	English
Pages (from-to)	109-129
Number of pages	21
Journal	Arkivoc
Volume	2004
Issue number	4
Publication status	Published - 2004

Keywords

Alkene ligands
Catalysis
Heterocycles
Macrocycles
Olefin complexes

Cite this

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title = "15-Membered triolefinic macrocycles, their coordination chemistry with transition metals, and the catalytic properties of their palladium metal complexes. A review",

abstract = "(E,E,E)-1,6,11-Tris(arenesulfonyl)-1,6,11-triazacyclopentadeca-3,8, 11-trienes, 1, are prepared from arenesulfonamides and trans-1,4-dibromo-2-butene. Macrocycles 1 coordinate palladium(0), platinum(0), and silver(I), and the palladium complexes are useful and reutilizable catalysts or precatalysts in Suzuki cross-couplings, butadiene telomerizations, hydroarylation of alkynes, and in the Heck reaction. Structurally related macrocycles are also available by similar synthetic procedures.",

keywords = "Alkene ligands, Catalysis, Heterocycles, Macrocycles, Olefin complexes",

author = "Marcial Moreno-Ma{\~n}as and Roser Pleixats and Anna Roglans and Sebasti{\'a}n, \{Rosa M.\} and Adelina Vallribera",

year = "2004",

language = "English",

volume = "2004",

pages = "109--129",

journal = "Arkivoc",

issn = "1424-6376",

publisher = "Arkat",

number = "4",

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TY - JOUR

T1 - 15-Membered triolefinic macrocycles, their coordination chemistry with transition metals, and the catalytic properties of their palladium metal complexes. A review

AU - Moreno-Mañas, Marcial

AU - Pleixats, Roser

AU - Roglans, Anna

AU - Sebastián, Rosa M.

AU - Vallribera, Adelina

PY - 2004

Y1 - 2004

N2 - (E,E,E)-1,6,11-Tris(arenesulfonyl)-1,6,11-triazacyclopentadeca-3,8, 11-trienes, 1, are prepared from arenesulfonamides and trans-1,4-dibromo-2-butene. Macrocycles 1 coordinate palladium(0), platinum(0), and silver(I), and the palladium complexes are useful and reutilizable catalysts or precatalysts in Suzuki cross-couplings, butadiene telomerizations, hydroarylation of alkynes, and in the Heck reaction. Structurally related macrocycles are also available by similar synthetic procedures.

AB - (E,E,E)-1,6,11-Tris(arenesulfonyl)-1,6,11-triazacyclopentadeca-3,8, 11-trienes, 1, are prepared from arenesulfonamides and trans-1,4-dibromo-2-butene. Macrocycles 1 coordinate palladium(0), platinum(0), and silver(I), and the palladium complexes are useful and reutilizable catalysts or precatalysts in Suzuki cross-couplings, butadiene telomerizations, hydroarylation of alkynes, and in the Heck reaction. Structurally related macrocycles are also available by similar synthetic procedures.

KW - Alkene ligands

KW - Catalysis

KW - Heterocycles

KW - Macrocycles

KW - Olefin complexes

UR - https://www.scopus.com/pages/publications/2942607092

M3 - Review article

AN - SCOPUS:2942607092

SN - 1424-6376

VL - 2004

SP - 109

EP - 129

JO - Arkivoc

JF - Arkivoc

IS - 4

ER -

15-Membered triolefinic macrocycles, their coordination chemistry with transition metals, and the catalytic properties of their palladium metal complexes. A review

Abstract

Keywords

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