Switchable catalysis with a light-responsive cavitand

Orion B. Berryman; Aaron C. Sather; Agustí Lledó; Julius Rebek

doi:10.1002/anie.201105374

Switchable catalysis with a light-responsive cavitand

Orion B. Berryman
, Aaron C. Sather
, Agustí Lledó
, Julius Rebek

Scripps Research Institute
Institute for Research in Biomedicine

Producció científica: Contribució a revista › Article científic › Avaluat per experts

104 Cites (Scopus)

Resum

Catalytic guest stars: A cavitand with an azobenzene wall adopts an introverted shape when irradiated with UV light. This conformation has been characterized in solution and the solid state and is used to control guest binding. By incorporating an organocatalyst guest, the rate of the Knoevenagel condensation is controlled with light.

Idioma original	Anglès
Pàgines (de-a)	9400-9403
Nombre de pàgines	4
Revista	Angewandte Chemie International Edition
Volum	50
Número	40
DOIs	https://doi.org/10.1002/anie.201105374
Estat de la publicació	Data de publicació - 26 de set. 2011
Publicat externament	Sí

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10.1002/anie.201105374

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@article{f6fbf75581a04d86ae95db52692c4746,

title = "Switchable catalysis with a light-responsive cavitand",

abstract = "Catalytic guest stars: A cavitand with an azobenzene wall adopts an introverted shape when irradiated with UV light. This conformation has been characterized in solution and the solid state and is used to control guest binding. By incorporating an organocatalyst guest, the rate of the Knoevenagel condensation is controlled with light.",

keywords = "Knoevenagel condensation, cavitands, host-guest systems, photo-switches, supramolecular catalysis",

author = "Berryman, \{Orion B.\} and Sather, \{Aaron C.\} and Agust{\'i} Lled{\'o} and Julius Rebek",

year = "2011",

month = sep,

day = "26",

doi = "10.1002/anie.201105374",

language = "English",

volume = "50",

pages = "9400--9403",

journal = "Angewandte Chemie International Edition",

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publisher = "Wiley-VCH",

number = "40",

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TY - JOUR

T1 - Switchable catalysis with a light-responsive cavitand

AU - Berryman, Orion B.

AU - Sather, Aaron C.

AU - Lledó, Agustí

AU - Rebek, Julius

PY - 2011/9/26

Y1 - 2011/9/26

N2 - Catalytic guest stars: A cavitand with an azobenzene wall adopts an introverted shape when irradiated with UV light. This conformation has been characterized in solution and the solid state and is used to control guest binding. By incorporating an organocatalyst guest, the rate of the Knoevenagel condensation is controlled with light.

AB - Catalytic guest stars: A cavitand with an azobenzene wall adopts an introverted shape when irradiated with UV light. This conformation has been characterized in solution and the solid state and is used to control guest binding. By incorporating an organocatalyst guest, the rate of the Knoevenagel condensation is controlled with light.

KW - Knoevenagel condensation

KW - cavitands

KW - host-guest systems

KW - photo-switches

KW - supramolecular catalysis

UR - https://www.scopus.com/pages/publications/80053160629

U2 - 10.1002/anie.201105374

DO - 10.1002/anie.201105374

M3 - Scientific article

C2 - 21905192

AN - SCOPUS:80053160629

SN - 1433-7851

VL - 50

SP - 9400

EP - 9403

JO - Angewandte Chemie International Edition

JF - Angewandte Chemie International Edition

IS - 40

ER -

Switchable catalysis with a light-responsive cavitand

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