Reaction of Diphenyl Phosphorochloridate with Amide Enolates: A new and convenient synthesis of 2‐monosubstituted 3‐(n‐methyl‐n ‐phenylamino)‐2H‐azirines

José M. Villalgordo; Heinz Heimgartner

doi:10.1002/hlca.19920750612

Reaction of Diphenyl Phosphorochloridate with Amide Enolates: A new and convenient synthesis of 2‐monosubstituted 3‐(n‐methyl‐n ‐phenylamino)‐2H‐azirines

José M. Villalgordo
, Heinz Heimgartner

University of Zurich

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Resum

Reaction of diphenyl phosphorochloridate with amide enolates and subsequent treatment with NaN₃ leads to 2‐monosubstituted 3‐amino‐2H ‐azirines 5 in moderate yields. The reactivity of these azirines is briefly explored.

Idioma original	Anglès
Pàgines (de-a)	1866-1871
Nombre de pàgines	6
Revista	Helvetica Chimica Acta
Volum	75
Número	6
DOIs	https://doi.org/10.1002/hlca.19920750612
Estat de la publicació	Data de publicació - 2 d’oct. 1992
Publicat externament	Sí

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10.1002/hlca.19920750612

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@article{c983787c93d845e8bcc580b71211d6ce,

title = "Reaction of Diphenyl Phosphorochloridate with Amide Enolates: A new and convenient synthesis of 2‐monosubstituted 3‐(n‐methyl‐n ‐phenylamino)‐2H‐azirines",

abstract = "Reaction of diphenyl phosphorochloridate with amide enolates and subsequent treatment with NaN3 leads to 2‐monosubstituted 3‐amino‐2H ‐azirines 5 in moderate yields. The reactivity of these azirines is briefly explored.",

author = "Villalgordo, \{Jos{\'e} M.\} and Heinz Heimgartner",

year = "1992",

month = oct,

day = "2",

doi = "10.1002/hlca.19920750612",

language = "English",

volume = "75",

pages = "1866--1871",

journal = "Helvetica Chimica Acta",

issn = "0018-019X",

publisher = "Wiley-Blackwell",

number = "6",

}

Reaction of Diphenyl Phosphorochloridate with Amide Enolates: A new and convenient synthesis of 2‐monosubstituted 3‐(n‐methyl‐n ‐phenylamino)‐2H‐azirines. / Villalgordo, José M.; Heimgartner, Heinz.
In: Helvetica Chimica Acta, Vol. 75, Núm. 6, 02.10.1992, pàg. 1866-1871.

Producció científica: Contribució a revista › Article científic › Avaluat per experts

TY - JOUR

T1 - Reaction of Diphenyl Phosphorochloridate with Amide Enolates

T2 - A new and convenient synthesis of 2‐monosubstituted 3‐(n‐methyl‐n ‐phenylamino)‐2H‐azirines

AU - Villalgordo, José M.

AU - Heimgartner, Heinz

PY - 1992/10/2

Y1 - 1992/10/2

N2 - Reaction of diphenyl phosphorochloridate with amide enolates and subsequent treatment with NaN3 leads to 2‐monosubstituted 3‐amino‐2H ‐azirines 5 in moderate yields. The reactivity of these azirines is briefly explored.

AB - Reaction of diphenyl phosphorochloridate with amide enolates and subsequent treatment with NaN3 leads to 2‐monosubstituted 3‐amino‐2H ‐azirines 5 in moderate yields. The reactivity of these azirines is briefly explored.

UR - https://www.scopus.com/pages/publications/0001122614

U2 - 10.1002/hlca.19920750612

DO - 10.1002/hlca.19920750612

M3 - Scientific article

AN - SCOPUS:0001122614

SN - 0018-019X

VL - 75

SP - 1866

EP - 1871

JO - Helvetica Chimica Acta

JF - Helvetica Chimica Acta

IS - 6

ER -

Reaction of Diphenyl Phosphorochloridate with Amide Enolates: A new and convenient synthesis of 2‐monosubstituted 3‐(n‐methyl‐n ‐phenylamino)‐2H‐azirines

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