A simple catalytic system based on PdCl2(CH3CN) 2 in water for cross-coupling reactions using diazonium salts

Ouissam El Bakouri; Martí Fernández; Sandra Brun; Anna Pla-Quintana; Anna Roglans

doi:10.1016/j.tet.2013.09.010

A simple catalytic system based on PdCl₂(CH₃CN) ₂ in water for cross-coupling reactions using diazonium salts

Ouissam El Bakouri
, Martí Fernández
, Sandra Brun
, Anna Pla-Quintana
, Anna Roglans

Producció científica: Contribució a revista › Article científic › Avaluat per experts

23 Cites (Scopus)

Resum

Aryl-heteroaryl and heteroaryl-heteroaryl compounds are obtained through the Suzuki-Miyaura cross-coupling reactions between diazonium salts and potassium trifluoroborates using PdCl₂(CH₃CN)₂ as the catalyst in water and in the absence of any additive, ligand or base. In addition, the same mild catalytic system is effective for the Matsuda-Heck reaction between several monoolefins with aryldiazonium salts.

Idioma original	Anglès
Pàgines (de-a)	9761-9765
Nombre de pàgines	5
Revista	Tetrahedron
Volum	69
Número	46
DOIs	https://doi.org/10.1016/j.tet.2013.09.010
Estat de la publicació	Data de publicació - 18 de nov. 2013

Accés al document

10.1016/j.tet.2013.09.010

https://hdl.handle.net/10256/11338

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title = "A simple catalytic system based on PdCl2(CH3CN) 2 in water for cross-coupling reactions using diazonium salts",

abstract = "Aryl-heteroaryl and heteroaryl-heteroaryl compounds are obtained through the Suzuki-Miyaura cross-coupling reactions between diazonium salts and potassium trifluoroborates using PdCl2(CH3CN)2 as the catalyst in water and in the absence of any additive, ligand or base. In addition, the same mild catalytic system is effective for the Matsuda-Heck reaction between several monoolefins with aryldiazonium salts.",

keywords = "Aqueous medium, Cross-coupling reactions, Diazonium salts, Palladium",

author = "\{El Bakouri\}, Ouissam and Mart{\'i} Fern{\'a}ndez and Sandra Brun and Anna Pla-Quintana and Anna Roglans",

year = "2013",

month = nov,

day = "18",

doi = "10.1016/j.tet.2013.09.010",

language = "English",

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pages = "9761--9765",

journal = "Tetrahedron",

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TY - JOUR

T1 - A simple catalytic system based on PdCl2(CH3CN) 2 in water for cross-coupling reactions using diazonium salts

AU - El Bakouri, Ouissam

AU - Fernández, Martí

AU - Brun, Sandra

AU - Pla-Quintana, Anna

AU - Roglans, Anna

PY - 2013/11/18

Y1 - 2013/11/18

N2 - Aryl-heteroaryl and heteroaryl-heteroaryl compounds are obtained through the Suzuki-Miyaura cross-coupling reactions between diazonium salts and potassium trifluoroborates using PdCl2(CH3CN)2 as the catalyst in water and in the absence of any additive, ligand or base. In addition, the same mild catalytic system is effective for the Matsuda-Heck reaction between several monoolefins with aryldiazonium salts.

AB - Aryl-heteroaryl and heteroaryl-heteroaryl compounds are obtained through the Suzuki-Miyaura cross-coupling reactions between diazonium salts and potassium trifluoroborates using PdCl2(CH3CN)2 as the catalyst in water and in the absence of any additive, ligand or base. In addition, the same mild catalytic system is effective for the Matsuda-Heck reaction between several monoolefins with aryldiazonium salts.

KW - Aqueous medium

KW - Cross-coupling reactions

KW - Diazonium salts

KW - Palladium

UR - https://www.scopus.com/pages/publications/84885179412

U2 - 10.1016/j.tet.2013.09.010

DO - 10.1016/j.tet.2013.09.010

M3 - Scientific article

AN - SCOPUS:84885179412

SN - 0040-4020

VL - 69

SP - 9761

EP - 9765

JO - Tetrahedron

JF - Tetrahedron

IS - 46